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Zero Liquid Discharge Process for Power Plant Desulfurization Wastewater

Zero Liquid Discharge Process for Power Plant Desulfurization Wastewater

Managing High-Salinity, High-Hardness Wastewater for Compliant Discharge and Resource Conservation

Introduction

With tightening environmental standards for coal-fired power plants, desulfurization wastewater, as a terminal effluent, has raised significant concerns regarding volume reduction and zero discharge. Such wastewater typically contains high salinity, calcium-magnesium hardness, and heavy metals, making it difficult for conventional treatments to achieve stable compliance. Plum Membrane leverages core technologies such as PEK tubular membranes, two-stage nanofiltration, and HRCC high-recovery concentration to provide a comprehensive zero liquid discharge and resource utilization solution, ensuring long-term, stable operations.

Background & Challenges


Desulfurization wastewater originates mainly from wet flue gas desulfurization and presents the following challenges:
 

High calcium and magnesium hardness causing scaling
High sulfate and chloride levels (approximately 20,000 mg/L), causing severe corrosion
Contains heavy metals (arsenic, selenium, mercury, cadmium), and high silica content
High Total Dissolved Solids (TDS), posing difficulties for traditional desalination processes

Typical Feed Water Characteristics


High hardness (Ca²⁺, Mg²⁺)
High salinity (Na⁺, Cl⁻, SO₄²⁻)
Elevated COD and suspended solids
Presence of various heavy metals (arsenic, selenium, mercury, etc.)

Process Flow


Process Highlight


Two-Stage Softening and Silica Removal

Ensures product water hardness <50 mg/L, calcium-magnesium <10 mg/L, and silica <20 mg/L, effectively reducing scaling risks.

Calcium Sulfate Precipitation for Sulfate Removal

Sulfate ions are precipitated as calcium sulfate via excess calcium ion reactions, removed by a plate-and-frame filter press system.

Nanofiltration Salt Separation

NF concentrate maintains a calcium sulfate to sodium chloride ratio >10:1, reducing scaling potential; NF permeate has a sodium chloride to sodium sulfate ratio >60:1, ensuring high purity and stability of crystallized salts.

High Automation and Stability

Highly automated process capable of adapting to water quality fluctuations, ensuring reliability and stable long-term operation.

Applications


Coal-fired power plant desulfurization wastewater
Flue gas treatment wastewater in petrochemical industries
High-hardness, high-salinity terminal wastewater in the power industry
Industrial wastewater systems requiring heavy metal removal and high-TDS management

Case Photos


Zero Liquid Discharge Process for Power Plant Desulfurization Wastewater

Zero Liquid Discharge Process for Power Plant Desulfurization Wastewater

Zero Liquid Discharge Process for Power Plant Desulfurization Wastewater

Zero Liquid Discharge Process for Power Plant Desulfurization Wastewater

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Anhui Plum Membrane Technology Co., Ltd.

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