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Landfill Leachate Treatment – Ammonia Stripping Process

Landfill Leachate Treatment – Ammonia Stripping Process

Integrated solution for high-ammonia leachate: volume reduction and resource recovery to achieve both discharge compliance and nitrogen load control.

Introduction

Landfill leachate is a complex, high strength wastewater featuring elevated ammonia, high salinity, and a low C/N ratio; in aging landfills it is often unsuitable for conventional biological treatment. To achieve nitrogen reduction, upgraded effluent quality, and resource recovery, Plum Membrane has developed a full scale treatment scheme centered on ammonia stripping.

Background & Challenges


Ammonia levels of 3,500–3,900 mg/L, COD ≈ 5,000 mg/L, and low C/N ratio, resulting in poor biodegradability;
Biological systems prone to instability and nitrogen exceedance;
Membrane systems requiring high carbon dosing and incurring elevated costs;
Conventional stripping towers prone to fouling, corrosion, and high energy consumption.

Typical Feed Water Characteristics


Aging leachate with high ammonia nitrogen (3500–3900 mg/L)
High total nitrogen (up to 4300 mg/L)
Wide pH range (6–9)
Moderate low COD (≈5000 mg/L) with insufficient C/N ratio
Complex organics with sulfides, metal ions, and particulates

Process Flow


High-ammonia wastewater is first collected in a storage tank and preheated via a heat exchanger before entering the desorption reactor. There, it is heated with saturated steam to facilitate the release of ammonia nitrogen from the liquid phase into the gas phase. The wastewater then flows into the ammonia stripping tower, where enhanced gas-liquid contact ensures efficient ammonia removal. The stripped liquid is cooled by a deep cooler and sent to a product water tank for further treatment or discharge.

The ammonia gas released during desorption is cooled by a condenser. In the gas-liquid separation tower, uncondensed gases and condensate are separated. The condensate is recirculated, while uncondensed ammonia gas is sent to an ammonia absorber and then reacted with carbon dioxide in a carbonation tower to produce ammonium bicarbonate slurry. This slurry enters a crystal tank, where it undergoes centrifugal separation and packaging to yield a recoverable ammonium bicarbonate product. The remaining tail gas passes through acid dosing, tail gas scrubbing, and recovery units before discharge. A draft fan ensures system stability and prevents gas leakage.

This process achieves high ammonia removal efficiency (≥75%) and converts ammonia into a reusable by-product, ammonium bicarbonate, significantly reducing downstream treatment loads and operational costs, supporting full leachate treatment, resource utilization, and near-zero discharge goals.

Design Influent and Effluent Water Quality


No.

Parameter

Unit

Influent

Effluent

Removal

1

NH₃N

mg/L

≤3500

≤875

≥75 %

2

TN

mg/L

≤4300

≤1675

≥61 %

3

pH

6 – 9

6 – 9

Process Highlight


High Ammonia Removal Efficiency: The system achieves overall ammonia removal ≥75%, significantly reducing the ammonia load on downstream units
Innovative Internal Design: Uses anti-clog and anti-scaling tray structures instead of traditional packing to support long-term stable operation
Highly Integrated System: Combines condensation absorption with thermal integration to reduce energy consumption and improve system synergy
Safe and Stable Operation: Automated control system ensures coordinated, efficient, and stable operation under varying loads
High Resource Recovery: 20% of the concentrate is treated through salt recovery; both crystallized salts and ammonia are reused as valuable resources

Applications


Aging landfill leachate nitrogen reduction
Compliance treatment for high-ammonia leachate from industrial solid waste landfills
Integrated leachate treatment from incineration fly ash landfills
High-strength leachate treatment in hazardous waste landfills and integrated waste parks

Case Photos


Landfill Leachate Treatment – Ammonia Stripping Process

Landfill Leachate Treatment – Ammonia Stripping Process

Landfill Leachate Treatment – Ammonia Stripping Process

Landfill Leachate Treatment – Ammonia Stripping Process

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Anhui Plum Membrane Technology Co., Ltd.

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