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Landfill Leachate Treatment — All-Nanofiltration (NF) Process

Landfill Leachate Treatment — All-Nanofiltration (NF) Process

An RO/DTRO-free NF solution achieving ≥96.875% water recovery, minimizing high-salinity concentrate and reducing operating costs.

Introduction

Landfill leachate, characterized by high ammonia nitrogen, COD, heavy metals, and refractory organics, is considered one of the most challenging industrial wastewaters. With increasingly strict environmental standards, traditional processes struggle to achieve full-scale treatment and resource utilization. Plum Membrane has developed a nanofiltration-based full-scale solution integrating proprietary membrane systems and core technologies, enabling brine-free discharge, resource recovery, and compliant effluent.

Background & Challenges


Leachate originates from diverse sources and features highly variable composition. Aging leachate often contains 3500–4000 mg/L ammonia nitrogen and COD levels above 4000 mg/L, with severely imbalanced C/N ratios that hinder biological treatment. Conventional processes typically rely on RO, which generates highly saline concentrate, increasing downstream treatment complexity, cost, and carbon footprint.
This solution integrates membrane separation, salt separation, and evaporation crystallization to achieve truly full-scale treatment.

Typical Feed Water Characteristics


High NH₃–N, high COD, high hardness, and high alkalinity — difficult to treat.
Very low C/N ratio, requiring substantial external carbon dosing; high costs and challenges in meeting biological treatment requirements.
Coexistence of young and mature leachate; simultaneous presence of organics, colloids, and heavy metals leads to complex influent characteristics.
Leachate concentrate with elevated COD and salinity, posing membrane fouling risks and increasing operating expenses.

Process Flow


Fresh and aged landfill leachate first undergo separate pretreatment, precision filtration, and deammonification pretreatment units to remove large particulate suspended solids, colloids, ammonia nitrogen, and other pollutants, while adjusting the carbon-to-nitrogen ratio (6:1-10:1) to ensure stable water quality for subsequent systems. The water then enters the MBR system for further removal of organic matter and ammonia nitrogen, yielding high-quality ultrafiltrate that can be partially utilized for humic acid recovery (as organic or compound fertilizers). The MBR-treated leachate proceeds to the nanofiltration concentration system (80%), where the permeate is recycled internally, and the concentrate is divided into two streams entering the downstream membrane separation system (approximately 16.875% and 19.5%), enabling deep separation of salts and organics. Finally, it enters the evaporation crystallization system to produce high-purity crystalline salts, with the byproduct liquor processed through carbon dioxide and carbonization units to yield ammonium bicarbonate, which is centrifuged and packaged for use as a byproduct. The entire process achieves full quantitative closed-loop treatment of leachate without the need for high-pressure membrane processes such as RO or DTRO, eliminating high-salinity concentrate discharge, with a total system recovery rate exceeding 99.5%, maximizing resource recovery of water and salts, and truly attaining a "near-zero discharge" objective.

Design Influent and Effluent Water Quality


Treatment Unit

Item

COD (mg/L)

BOD₅ (mg/L)

NH₃-N (mg/L)

TN (mg/L)

SS (mg/L)

NO₃-N (mg/L)

3200 m³/d Leachate Treatment System

Influent

800–1000

20–30

≤10

40–50

≤2

20–30

640 m³/d Concentrate Treatment System

Influent

3500–4000

20–30

≤10

40–50

≤2

20–30

Discharge Standard

Product Water

40–60

20

≤8

≤20

0

15

Process Highlight


All-nanofiltration (NF) scheme; no RO/DTRO required; no discharge of high-salinity brine.
Overall membrane-stage recovery >96.875%; plant-wide water recovery up to 99.5% with evaporation & crystallization.
N+1 redundancy for continuous, stable, unattended operation.
Enables organic-fertilizer by-product recovery, salt resource recovery, and compliant effluent discharge.
Handles mixed-source leachate with high operational flexibility and low O&M cost.

Case Photos


Landfill Leachate Treatment — All-Nanofiltration (NF) Process

Landfill Leachate Treatment — All-Nanofiltration (NF) Process

Landfill Leachate Treatment — All-Nanofiltration (NF) Process

Landfill Leachate Treatment — All-Nanofiltration (NF) Process

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Anhui Plum Membrane Technology Co., Ltd.

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