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Lithium Extraction and Resource Recovery from Salt Lakes and Ores Using Membrane Processes

Lithium Extraction and Resource Recovery from Salt Lakes and Ores Using Membrane Processes

Multi-stage Membrane Separation Integrated with Adsorption for Highly Selective Lithium Recovery and Byproduct Utilization in Complex Systems

Introduction

Salt lakes and mineral ores are currently the two main lithium resources. Salt lake brines typically exhibit low lithium concentrations, very high magnesium-to-lithium ratios, and numerous impurities, whereas ore-derived lithium extraction solutions contain high concentrations of sulfate and complex salts. Addressing the difficulty in selective lithium extraction and handling of byproduct streams, Plum Membrane developed a membrane-based lithium recovery approach utilizing membrane integration, adsorption, salt separation, and concentration technologies, delivering an environmentally friendly, continuous, and high-recovery process.

Background & Challenges


Complex lithium-containing streams with high impurity ion concentrations significantly interfere with lithium enrichment.
Salt lake brines have Mg/Li ratios often exceeding 60:1, necessitating highly selective separation techniques to enhance lithium recovery.
Ions such as fluoride, aluminum, and sulfate readily cause precipitation or membrane scaling.
Presence of residual extraction agents and complexity of byproduct handling limit effective resource utilization.

Typical Feed Water Characteristics


Mineral Ore Extraction:

High sulfate concentration due to sulfuric acid roasting and water leaching, complicated salt composition
Presence of fluoride and aluminum ions leads to scaling and challenging separation
Requires pretreatment clarification due to residual extractants or side reactions

Salt Lake Extraction:

High TDS (>150 g/L), low Li⁺ content (0.02~0.08%)
Mg/Li ratio often >60:1, with impurities including K⁺, Na⁺, Ca²⁺, Fe³⁺, boron, rubidium, cesium, etc.
Difficult separation and low lithium recovery rate

Process Flow


The lithium extraction process is flexibly configured according to salt lake or mineral ore pathways, covering the entire process from pretreatment to product crystallization. Initially, clarification and PEK tubular microfiltration efficiently remove suspended solids and colloids, protecting downstream operations. Highly selective adsorbents then remove interfering ions such as magnesium and aluminum. Subsequently, multi-stage membrane systems (MF/NF/RO/ED) achieve precise separation of monovalent and divalent ions, enriching lithium ions. Further resin softening and evaporation concentration enhance lithium content, and lithium chloride or lithium carbonate is produced through precipitation or crystallization. Residual brine undergoes salt separation, enabling secondary salt resource recovery or compliant discharge. The integrated process is adaptable, precise, and resource-efficient, suitable for various lithium resource development scenarios.

Process Highlight


PEK Tubular Membrane Clarification :MF permeate SS <1 mg/L, improving adsorbent lifespan and efficiency.
Multi-stage Membrane for Salt Separation: MF+NF+ED series operation precisely separates monovalent/multivalent ions, optimizing lithium concentrate quality.
High Concentration and Low Energy Recovery: HRCC technology reduces energy consumption during concentration, increasing lithium levels and reducing residual brine volumes.
Lithium Precipitation/Crystallization and Byproduct Recovery: Brine salt separation ratio >60:1, producing high-purity crystallized byproducts suitable for reuse.

Applications


Lithium extraction pre-concentration from salt lakes
Treatment of spodumene/lepidolite lithium ore extraction wastewater
Lithium extraction from high Mg/Li ratio brines
Volume reduction and resource utilization of lithium extraction byproducts

Case Photos


Lithium Extraction and Resource Recovery from Salt Lakes and Ores Using Membrane Processes

Lithium Extraction and Resource Recovery from Salt Lakes and Ores Using Membrane Processes

Lithium Extraction and Resource Recovery from Salt Lakes and Ores Using Membrane Processes

Lithium Extraction and Resource Recovery from Salt Lakes and Ores Using Membrane Processes

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Anhui Plum Membrane Technology Co., Ltd.

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